Transition-metal complexes with (CF3)2CN–as ligand and a tautomeric hydrogen transfer from metal to ligand
- 1 January 1971
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 5,p. 215-216
- https://doi.org/10.1039/c29710000215
Abstract
Reactions of appropriate metal chlorides and (CF3)2CNLi (RLi) afford the novel ketimides (π-C5H5)2Ti(R)Cl, (Ph3P)3RhR, cis-(Ph3P)2Pt(R)Cl, trans-(Ph3P)2Pt(R)H, cis-(Me2PhP)2Pt(R)Cl, cis-(Me2PhP)2PtR2, and trans-(Me2PhP)2Pt(R)H; and trans-(Ph3P)2Pt-(R)H is isomerised by heating with Ph3P in benzene to yield (Ph3P)2Pt[HNC(CF3)2].Keywords
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