Investigation on the reflection and transmission properties of complex absorbing potentials
- 22 July 1996
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 105 (4) , 1409-1419
- https://doi.org/10.1063/1.472003
Abstract
The reflection and transmission properties of different complex absorbing potentials (CAPs) are studied using WKB and scaling procedures which make the results transferable to any mass and kinetic energy. Explicit formulas are obtained which describe the reflection and transmission properties of monomial CAPs −iηxn with high accuracy. These properties are now well understood. The approximate results are compared to exact analytical results available for quadratic CAPs, and to numerical results obtained by wave packet propagation followed by an energy resolved analysis. The approximate, but accurate, description of the action of the CAP is finally used to determine optimal CAP parameters. CAP length, strength, and order can now be chosen in such a way that the sum of reflection and transmission is minimized. Optimal parameters are compiled for different energies and energy intervals.Keywords
This publication has 26 references indexed in Scilit:
- Reflection-free complex absorbing potentialsJournal of Physics B: Atomic, Molecular and Optical Physics, 1995
- Propagation Methods for Quantum Molecular DynamicsAnnual Review of Physical Chemistry, 1994
- Perfect absorbers for stationary and wavepacket scatteringJournal of Physics A: General Physics, 1994
- A new computational algorithm for Green's functions: Fourier transform of the Newton polynomial expansionComputer Physics Communications, 1993
- Reflection and transmission of waves by a complex potential—a semiclassical Jeffreys–Wentzel–Kramers–Brillouin treatmentThe Journal of Chemical Physics, 1992
- The application of time-dependent wavepacket methods to reactive scatteringComputer Physics Communications, 1991
- A new accurate (time-independent) method for treating three-dimensional reactive collisions: The application of optical potentials and projection operatorsThe Journal of Chemical Physics, 1990
- A new time-independent approach to the study of atom-diatom reactive collisions: theory and applicationThe Journal of Physical Chemistry, 1990
- On the calculation of S-matrix poles using the Siegert methodJournal of Physics B: Atomic and Molecular Physics, 1982
- On the Connection Formulas and the Solutions of the Wave EquationPhysical Review B, 1937