Manganese carbonyl and phase transfer catalysed, stereospecific hydroacylation of allenes to α,β-unsaturated ketones
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 8-9
- https://doi.org/10.1039/c39910000008
Abstract
Phase transfer (5 mmol dm–3 NaOH, CH2Cl2, cetyltrimethylammonium bromide) catalysed reaction of allenes with carbon monoxide, decacarbonyldimanganese and methyl iodide affords α,β-unsaturated ketones in a stereospecific process.Keywords
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