APPLICATION OF THE PFEIFFER EFFECT TO PARTIAL RESOLUTION OF TRIS(ACETYLACETONATO)COBALT(III)
- 5 March 1977
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 6 (3) , 319-320
- https://doi.org/10.1246/cl.1977.319
Abstract
Partial resolution of neutral [Co(acac)3] was performed by extracting into 1,2-dichloroethane the complex formed when racemic Li[Co(acac)3] was mixed with Δ- or Λ-[Co(phen)3]Cl3 in water. This system is the first Pfeiffer-active system in which a dissymmetric metal complex serves as a chiral environment compound.This publication has 5 references indexed in Scilit:
- Circular dichroism and absolute configuration of tris(acetyl-acetonato) cobalt(III)Inorganic and Nuclear Chemistry Letters, 1976
- Stereoselectivity in electron-transfer reactionsInorganic Chemistry, 1976
- Absolute configuration of (+)D-trisphenanthrolinecobalt(III)Journal of the American Chemical Society, 1975
- Crystal and molecular structure of 5,12a-diacetyloxytetracyclineJournal of the American Chemical Society, 1971
- The application of the Pfeiffer effect to the resolution of dissymmetric coordination compoundsJournal of the American Chemical Society, 1968