The Preparation of Aryl Alkyl Ethers from Fluoroarenetricarbonylchromium Complexes
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 16 (10) , 1363-1369
- https://doi.org/10.1080/00945718608071410
Abstract
The nucleophilic substitution of a number of di- and trisubstituted fluoroarenetricarbonylchromium complexes has been studied using the alkoxides derived from methyl, ethyl, isopropyl and t-butyl alcohols. In the first three cases the reactions proceed smoothly to give the expected aryl ethers, while in the t-butoxide case significant amounts of phenolic elimination products are also observed. Fluoride was displaced from arenes containing alkyl, methoxy, amino and alkylamino substituents.Keywords
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