Effects of background electrolyte composition and addition of selectors on separation selectivity in nonaqueous capillary electrophoresis
- 14 May 2003
- journal article
- review article
- Published by Wiley in Electrophoresis
- Vol. 24 (10) , 1499-1507
- https://doi.org/10.1002/elps.200305412
Abstract
This review gives a survey of the approaches employed to obtain, enhance and tune selectivity in nonaqueous capillary electrophoresis (NACE). Recent developments in NACE are described and the effects of background electrolyte composition and addition of selectors on separation selectivity are discussed. The use of one organic solvent, a mixture of several organic solvents or the use of additives to tune separation selectivity in NACE is presented and a list of relevant applications is included.Keywords
This publication has 69 references indexed in Scilit:
- Synergistic effects of ion-pairing in the enantiomeric separation of basic compounds with cyclodextrin derivatives in nonaqueous capillary electrophoresisElectrophoresis, 2003
- Enantioseparations using capillary electromigration techniques in nonaqueous buffersElectrophoresis, 2000
- Nonaqueous capillary electrophoresis: A versatile completion of electrophoretic separation techniquesElectrophoresis, 2000
- A Family of Single-Isomer, Sulfated γ-Cyclodextrin Chiral Resolving Agents for Capillary Electrophoresis. 1. Octakis(2,3-diacetyl-6-sulfato)-γ-cyclodextrinAnalytical Chemistry, 1999
- Capillary electrophoretic separation of weak base enantiomers using the single-isomer heptakis-(2,3-dimethyl-6-sulfato)-β-cyclodextrin as resolving agent and methanol as background electrolyte solventJournal of Pharmaceutical and Biomedical Analysis, 1998
- Method development in pharmaceutical analysis employing capillary electrochromatographyElectrophoresis, 1998
- Separation of Polycyclic Aromatic Hydrocarbons by Nonaqueous Capillary Electrophoresis Using Charge-Transfer Complexation with Planar Organic CationsAnalytical Chemistry, 1997
- Nonaqueous solvents in the on‐line capillary electrophoresis‐mass spectrometry analysis of drug metabolitesJournal of High Resolution Chromatography, 1994
- Determination of benzodiazepines by micellar electrokinetic chromatographyElectrophoresis, 1994
- Study of in Vivo pyrazoloacridine metabolism by capillary electrophoresis using isotachophoresis preconcentration in non‐aqueous separation bufferJournal of High Resolution Chromatography, 1993