On oxyhalogenation, acids, and non-mimics of bromoperoxidase enzymes
- 15 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Green Chemistry
- Vol. 2 (5) , 248-251
- https://doi.org/10.1039/b004927l
Abstract
In contrast to recent studies, molybdenum(VI) and vanadium(V) catalysed oxidative bromination reactions are found to depend on the presence of stoichiometric amounts of acid. Thus, recent reports on Lewis-acid catalysed oxybromination systems are re-examined. The relevance of these systems as bromoperoxidase enzyme mimics and also the potential application of enzymatic halogenation as a ‘green’ bromination option are discussed.Keywords
This publication has 0 references indexed in Scilit: