P(RNCH 2 CH 2 ) 3 N as Very Strong Non-Ionic Bases and Catalysts: Recent Advances and Applications
- 1 June 2002
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 177 (6-7) , 1621-1631
- https://doi.org/10.1080/10426500212298
Abstract
A rationale for the unusually strong Lewis basicity and catalytic activity of the title pro-azaphosphatranes is presented. Four stoichiometric and four catalytic uses of such pro-azaphosphatranes are described, as well as some unexpected reactions in which these bases take part. Mechanistic pathways are put forth for several of the transformations outlined.Keywords
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