SYNTHESIS AND PHYSICOCHEMICAL PROPERTIES OF POLYOXA(n)FERROCENOPHANES

Abstract
Three mononuclear polyoxa(n)ferrocenophanes (5) and binuclear polyoxa(n,n)ferrocenophanes (6) derived from 1,1′-bis(hydroxymethyl)ferrocene were synthesized and complexing ability of 5 with alkali and transition metal cations was measured by a solvent extraction method. Their complexing abilities were excellent with silver cation, although polyoxa(n)ferrocenophanes (1) derived from 1,1′-dihydroxyferrocene were decomposed by oxidation.

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