Fast time-resolved infrared spectroscopy of organometallic intermediates; detection of [(η5-C5H5)Fe(CO)2] and [(η5-C5H5)Fe(µ-CO)3Fe(η5-C5H5)] in room-temperature solution
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 972-974
- https://doi.org/10.1039/c39840000972
Abstract
A line-tunable CO laser has been use as a fast (1 µs) i.r. monitor to obtain spectra (2012–1710 cm–1) and lifetimes of [CpFe(CO)2](Cp =η5-C5H5) and [CpFe(µ-CO)3FeCp], formed during u.v.–visible flash photolysis of [CpFe(CO)2]2 in cyclohexane solution.Keywords
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