An electron diffraction investigation of gaseous chlorine dioxide

1 January 1970

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 46-48
https://doi.org/10.1039/j19700000046

Abstract

The electron diffraction pattern from gaseous chlorine dioxide at 10°C has been recorded over the range s= 0·86–35·00 Å^–1. Least-squares refinement gave the following structural parameters: r_g(1) for CIO = 1·475 Å, r_g(1) for OO = 2·525 Å, u_CIO= 0·035 Å, and u_OG= 0·063 Å. The corresponding estimated standard deviations are 0·003 Å, 0·022 Å, 1·7°, 0·004 Å, and 0·024Å, respectively. The vibrational amplitudes obtained are in agreement with values calculated from spectroscopic data.

Keywords

ELECTRON DIFFRACTION

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