Acylsilane Photolyses: 1,1-Diphenyl-1-Silacyclohexanone-2 in Cyclohexane
- 1 October 1975
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 53 (19) , 2874-2879
- https://doi.org/10.1139/v75-407
Abstract
Photolysis of the cyclic acylsilane 1,1-diphenyl-l-silacyclohexanone-2 yields 1,1-diphenyl-1-silacyclopentane and two dimeric products whose structures were established by chemical and spectroscopic methods. A mechanism involving a siloxycarbene intermediate which is trapped by a second acylsilane molecule, is proposed for the formation of the dimers.Keywords
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