New synthetic route to trialkyloxonium salts: alkylation of ethers with acyldialkyl cations
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 33-34
- https://doi.org/10.1039/c39760000033
Abstract
Acylium cations or complexes of acyl halides with nonmetal halides (e.g. PhCO+SbF6 – or PhCOClSbCl5) react at low temperature with an excess of alkyl ethers (e.g. Me2O or Et2O) giving the corresponding trialkyloxonium salts.Keywords
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