The System Pyridine-Pyrrole and the Association of Pyrrole
- 1 January 1955
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (1) , 93-97
- https://doi.org/10.1063/1.1740571
Abstract
Pyridine and pyrrole react together to form a 1:1 complex as shown by infrared, heat of reaction, viscosity, refractive index, and density data. The heat of formation of this complex is 3.8 kcal/mole. Pyrrole itself is associated, but, like the simple alcohols, cannot be represented by a simple equilibrium. The heat of dilution of pyrrole in CCl4 is 1.4 kcal/mole at infinite dilution.Keywords
This publication has 12 references indexed in Scilit:
- Infrared Study of the Effect of Solvent upon ν(NH) in PyrroleThe Journal of Chemical Physics, 1954
- A Study of the Association of Some Organic Acids by Infrared Absorption Measurements1Journal of the American Chemical Society, 1954
- On the Complexity of the N–H Stretching Vibration Band in Pyrrole and IndoleThe Journal of Chemical Physics, 1952
- The NH Stretching Vibration and NH–N Hydrogen Bonding in Several Aromatic CompoundsThe Journal of Chemical Physics, 1952
- Infrared Absorption Study of Hydrogen Bonding EquilibriaJournal of the American Chemical Society, 1951
- The heat of mixing of non‐polar liquidsRecueil des Travaux Chimiques des Pays-Bas, 1940
- Infrared Absorption Studies. IX. Bonding of Hydrogen in Nitrogen CompoundsJournal of the American Chemical Society, 1939
- The Heats of Mixing of Haloforms and Polyethylene Glycol EthersJournal of the American Chemical Society, 1938
- Über die sauren Eigenschaften einiger PyrroleEuropean Journal of Organic Chemistry, 1938
- The viscosities of liquid mixtures with pyrrole as a componentTransactions of the Faraday Society, 1937