Photolyse du chlorure d'éthyle gazeux en-dessous et au-dessus du potentiel d'ionisation
- 1 September 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (17) , 3098-3105
- https://doi.org/10.1139/v74-455
Abstract
Photolysis of gaseous ethyl chloride was performed at λ = 123.6 and 106.7–104.8 nm. There is no ionisation at 123.6 nm, while at 106.7–104.8 nm 40% of the absorbed light lead to ions. The identified products are the following: H2, CH4, C2H2, C2H4, C2H6, C3H6, C3H8, C4H10, CH3Cl, C2H3Cl, 2-C4H9Cl, 2,3-C4H8Cl2, and 1,3-C4H8Cl2. The effect of radical and electron scavengers on the product formation was studied. Charge neutralization reactions increase yields of H2, C2H2, and C2H4.Keywords
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