Intensities in Raman spectra IV. Intensity measurements for some chloromethanes
- 9 October 1956
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 237 (1209) , 197-211
- https://doi.org/10.1098/rspa.1956.0172
Abstract
The calculation of derivations of the invariants of the molecular polarizabilities from experimentally measured Raman intensities is critically discussed. Intensity formulae of an earlier paper are reviewed and a simplification introduced. Intensity measurements for the compounds CCl$_{4}$, CHCl$_{3}$ and CH$_{2}$Cl$_{2}$ are tabulated and discussed in relation to a bond polarizability theory. A modification of the simple theory is investigated.Keywords
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