Random-sequential adsorption of disks of different sizes
- 1 August 1992
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 46 (4) , 2029-2038
- https://doi.org/10.1103/physreva.46.2029
Abstract
The random-sequential adsorption of disks with two or more sizes onto a planar substrate has been investigated using computer simulations. For a binary mixture of large and small disks, we find that the large-disk coverage reaches its asymptotic value exponentially, while the small disk reaches its asymptotic value algebraically according to Feder’s law. For a uniform distribution of disk radii, the total coverage approaches its asymptotic value algebraically [ρ(∞)-ρ(t)∼, where ρ(t) is the coverage at time t], but the characteristic exponent p has an effective value smaller than 1/2. If the distribution of disk radii from which the disks are selected for attempted addition is Gaussian, then the exponent p has a very small effective value, and the distribution of adsorbed disks becomes very non-Gaussian if the initial Gaussian distribution is broad. Many of our simulation results can be understood in terms of the theoretical work of Talbot, Tarjus, and Schaff [Phys. Rev. A 40, 4808 (1980)], but other aspects of this work are beyond current theoretical approaches.
Keywords
This publication has 38 references indexed in Scilit:
- Random sequential adsorptionPublished by Elsevier ,2004
- Kinetics of irreversible adsorption of mixtures of pointlike and fixed-size particles: Exact resultsPhysical Review A, 1991
- Random sequential adsorption of unoriented rectangles onto a planeThe Journal of Chemical Physics, 1989
- Random sequential adsorption of lattice shapes onto a square latticeMolecular Physics, 1988
- Geometry of random sequential adsorptionJournal of Statistical Physics, 1986
- Cluster-size distributions for irreversible cooperative filling of lattices. II. Exact one-dimensional results for noncoalescing clustersPhysical Review A, 1985
- Competitive irreversible random one-, two-, three-, . . . point adsorption on two-dimensional latticesPhysical Review B, 1985
- Kinetics of large‐ligand binding to one‐dimensional lattices: theory of irreversible bindingBiopolymers, 1979
- Average nearest-neighbour spacing in a random dispersion of equal spheresPowder Technology, 1978
- Intramolecular Reaction between Neighboring Substituents of Vinyl PolymersJournal of the American Chemical Society, 1939