Fluorometric and Coulometric Analyses of Electron Transfer across Microdroplet/Water Interface
- 1 April 1994
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 23 (4) , 793-796
- https://doi.org/10.1246/cl.1994.793
Abstract
Electron transfer between ferrocene (FeCp) and Fe(III) across the droplet/water interface was studied by an optically transparent thin-layer electrode method. A time dependence of the FeCp concentration in the droplets caused by the interfacial electron transfer was discussed on the basis of coulometric analysis of Fe(II) or Fe(III) in the water phase and fluorometric analysis of FeCp in the droplets.This publication has 3 references indexed in Scilit:
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- Theory of electron-transfer rates across liquid-liquid interfacesThe Journal of Physical Chemistry, 1990
- Partitioning of para-phenylenediamines in oil-in-water emulsionsJournal of Colloid and Interface Science, 1987