Association of Aromatic Hydrocarbon Negative Ions with Alkali Ions. A Spectroscopic Investigation
- 15 March 1965
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 42 (6) , 1993-1999
- https://doi.org/10.1063/1.1696236
Abstract
From measurements of the electrical conductances of solutions of alkali—aromatic hydrocarbon salts in 2‐methyltetrahydrofuran, tetrahydrofuran, and 1,2‐dimethoxyethane, information has been gathered about the conditions under which the hydrocarbon negative ions are ``free'' or associated with the alkali counter ion. Guided by this knowledge, a study has been made of the influence of association on the electronic spectra of some negative ions in the polyacene and polyphenyl series.Keywords
This publication has 13 references indexed in Scilit:
- Electron Spin Resonance Study of the Pairing Theorem for Alternant Hydrocarbons : 13C Splittings in the Anthracene Positive and Negative IonsThe Journal of Chemical Physics, 1964
- Electronic Transitions of Some Polyacene Mononegative and Dinegative IonsThe Journal of Chemical Physics, 1964
- Line Width Alternation in the Electron Spin Resonance Spectrum of the Alkali Radical-Ion Complex of PyraceneJournal of the American Chemical Society, 1964
- The effect of alkali-metal ion association on the electronic spectra of the mononegative ions of naphthalene and anthraceneMolecular Physics, 1963
- Association Between Sodium and Naphthalenide Ions1Journal of the American Chemical Society, 1961
- Electronic spectra of the ketyls and related compounds. Part 1.—Origin of the spectra and cation-anion interactionTransactions of the Faraday Society, 1961
- Polarization of electronic transitions in aromatic hydorcarbon molecules and their mono- and di-valent ionsMolecular Physics, 1960
- Studies of organo-alkali metal complexes. Part 4.—Absorption spectra in the visible regionTransactions of the Faraday Society, 1960
- Electron transfer to aromatic moleculesDiscussions of the Faraday Society, 1960
- Reduction potentials of various aromatic hydrocarbons and their univalent anionsRecueil des Travaux Chimiques des Pays-Bas, 1956