BuSnCl3-Mediated Reaction of 3-(Tributylstannyl)cycloalkenes with Aldehydes. Highly erythro-Selective 2-Cyclopentenylation and 2-Cyclohexenylation of Aromatic Aldehydes
- 1 November 1992
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 21 (11) , 2221-2222
- https://doi.org/10.1246/cl.1992.2221
Abstract
3-(Butyldichlorostannyl)cyclopentene and 3-(butyldichlorostannyl)cyclohexene, which are prepared by the transmetalation of corresponding 3-(tributylstannyl)cycloalkene with BuSnCl3, react with aromatic aldehydes to give 2-cycloalkenylated products with excellent erythro-selectivity. However, the corresponding reaction with aliphatic aldehydes proceeded in only moderate erythro-selectivity.This publication has 5 references indexed in Scilit:
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