[CoII2L(NCS)2(SCN)2]: The First Cobalt Complex to Exhibit Both Exchange Coupling and Spin Crossover Effects
- 1 February 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (3) , 408-410
- https://doi.org/10.1002/(sici)1521-3773(19990201)38:3<408::aid-anie408>3.0.co;2-p
Abstract
A spin crossover transition (350 K, μeff=3.15 μB per Co atom; 4.5 K, μeff=0.70 μB per Co atom) and weak antiferromagnetic exchange (2 J=−11.7 cm−1) between the octahedral, doubly pyridazine bridged cobalt(II) ions are features of the structurally characterized complex [CoII2L(NCS)2(SCN)2] (the ligand L is shown).This publication has 0 references indexed in Scilit: