Enzyme-like enantioselective catalysis over chiral ‘molecular footprint’ cavities on a silica (alumina) gel surface
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 358-360
- https://doi.org/10.1039/c39920000358
Abstract
Chiral catalytic cavities were imprinted on a silica gel surface using a chiral template, N-benzoyl-(Nα-benzyloxycarbonyl)-L- alanineamide, by an imprinting procedure; these cavities display enatioselective catalysis in 2,4-dinitrophenolysis of the corresponding substrate, benzoic N-benzyloxycarbonyl-L-alanine anhydride.Keywords
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