Asymmetric hydrogenation catalysed by rhodium complexes of (2R,4R)-bis(diphenylphosphinomethyl)dioxolan. A stable rhodium dihydride derived from a chelating diphosphine complex
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 611-613
- https://doi.org/10.1039/c39790000611
Abstract
The mechanism of hydrogenation by rhodium complexes of the diphosphine, (2R,4R)-bis(diphenylphosphinomethyl)dioxolan, is deduced from phosphorus-31 n.m.r. studies.Keywords
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