In further pursuit of the carbene analogy: preparation and crystal structure of (N,N,N ′,N ′-tetramethylethylenediamine)potassium [cis-ethene-1,2-di(tert-butylamido)]gallate(I)
- 9 February 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 505-507
- https://doi.org/10.1039/b101016f
Abstract
Reduction of cis-ethene-1,2-di(tert-butylamido)gallium(III) chloride with metallic potassium in the presence of N,N,N′,N′-tetramethylethylenediamine gives the title compound which has a novel dimeric structure with the potassium cations η5-coordinated to the pseudo-carbene ring system of one monomer and η1-bonded to the gallium atom of the other.Keywords
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