Molecular polarisability. The Molar Kerr constants of aniline and of three substituted anilines in a variety of non-polar media
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 507-512
- https://doi.org/10.1039/j29680000507
Abstract
Molar Kerr constants are reported for aniline, 2,4,6-trimethylaniline, 2,4,6-tribromoaniline, and NN-dimethylaniline at infinite dilution in cyclohexane, carbon tetrachloride, benzene, and dioxan. Molecular polarisability parameters for aniline derived from ∞(mK2) measurements in the inert cyclohexane environment are used to investigate the polarity and polarisability changes brought about by the introduction of methyl and bromo-substituents in aniline, and the incidence of solute–solvent associations.Keywords
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