Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral ‘light fluorous’ phosphine ligand
- 14 June 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1220-1221
- https://doi.org/10.1039/b103074b
Abstract
The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2′-alkoxy-1,1′-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.Keywords
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