An examination of two solvation parameters: ΔCp≠ and 'm'
- 15 April 1977
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 55 (8) , 1319-1323
- https://doi.org/10.1139/v77-182
Abstract
The empirical 'm' values from the Grunwald–Winstein solvent correlation equation for SN displacement reactions show a fair correlation with corresponding ΔCP≠ values obtained from hydrolysis in water. The correlation plots separate according to the nature of the displaced groups, a consequence of different relative effects of anions on water structure. The mechanistic significance of the correlation is examined.Keywords
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