A new type of intramolecular group-transfer in steroid photochemistry. A contribution to the mechanism of the oxidative cyanohydrin–cyano-ketone rearrangement
- 1 January 1970
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 1002-1003
- https://doi.org/10.1039/c29700001002
Abstract
A radical-induced intramolecular transfer of a cyano-group is initiated by photolysis of a nitrite function situated in the ε-position with respect to the migrating group.Keywords
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