Conversion of 2-acetamido-2-deoxy-β-D-glucopyranose (N-acetylglucosamine) into 2-acetamido-2-deoxy-β-D-galactopyranose (N-acetylgalactosamine) using a biotransformation to generate a selectively deprotected substrate for SN2 inversion
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 235-237
- https://doi.org/10.1039/p19920000235
Abstract
A procedure is described for the conversion of N-acetylglucosamine 2 into N-acetyigalactosamine 1, in which use is made of a 4,6-acetyl migration in a precursor selectively deprotected by a biotransformation procedure.Keywords
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