Second-harmonic generation from mixed crystals of p-nitroaniline with substituted benzenes studied by the powder method
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 1 (4) , 591-593
- https://doi.org/10.1039/jm9910100591
Abstract
Second-harmonic generation (SHG) from mixed crystals of p-nitroaniline (p-NA) as guest and various substituted benzenes as host has been measured by the powder method with a 1064 nm YAG laser source. The SH intensities, which varied with crystallization conditions as well as host and mixing ratio, were as high as 100–189 × urea with p-dihydroxybenzene or p-dicyanobenzene as host. The SH intensity tends to increase with the size of the powdered crystals, implying a phase-matchable feature. The SHG activities were stable only at low (5 °C) temperature. It is speculated that epitaxial growth of p-NA crystals on the surface of host crystals would lead to an SHG-activity morphology.Keywords
This publication has 0 references indexed in Scilit: