Novel reactions of substituted 1-aza-4-oxobutadienes (α-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuNC(H)C(Me)O system and x-ray crystal structure of [EtZn(Et)(T-Bu)NC(H)C(Me)O]2
- 19 July 1983
- journal article
- research article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 251 (1) , c17-c21
- https://doi.org/10.1016/0022-328x(83)80256-3
Abstract
No abstract availableKeywords
This publication has 13 references indexed in Scilit:
- Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic synthesesJournal of Organometallic Chemistry, 1983
- 1,4-Diaza-1,3-butadiene (α-Diimine) Ligands: Their Coordination Modes and the Reactivity of Their Metal ComplexesPublished by Elsevier ,1982
- Regioselective ethyl transfer reactions between Diethylzinc and 1,4-Dialkyl-1,4-diaza-1,3-butadienes: Synthesis of EtZn[R(et)NCHCHNR]Journal of Organometallic Chemistry, 1982
- An unexpected ethyl transfer reaction between Et2Zn and DI(t-Butyl)-glyoxaldiimine (t-BuDAB). Studies of the persistent [EtZn(t-BuDAB)] radical which is in equilibrium with its CC coupled dimerJournal of Organometallic Chemistry, 1981
- Interaction of metal centres with the 1,4‐diaza‐1,3‐butadiene (α‐diimine) ligand. Versatile coordination chemistry and applications in organic synthesis and catalysisRecueil des Travaux Chimiques des Pays-Bas, 1981
- Diazabutadienes as ligandsJournal of Organometallic Chemistry, 1979
- Asymmetric synthesis of α-amino-acids from diastereomeric metal–imine complexesJournal of the Chemical Society, Chemical Communications, 1972
- Synthese asymetrique d'acides amines. Etude de l'addition d'organometalliques sur les imines glyoxyliques.Tetrahedron Letters, 1971
- Une nouvelle synthese D'α amino-acides. Synthese asymetrique de l'alanine.Tetrahedron Letters, 1970
- Reactions between some organozinc compounds and 2-dimethylaminoethanol, acetoxime, phenylisocyanate, and benzophenone. Some observations on the methylzinc methoxide tetramerJ. Chem. Soc. A, 1966