The preparation of Thiazolidine-2-thiones from N-alkylglucosylamines
- 1 January 1966
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 19 (3)
- https://doi.org/10.1071/ch9660445
Abstract
N-Alkylglucosylamines and carbon disulphide react to give 3-alkyl-5-hydroxy- 5-(D-arabino-tetrahydroxybutyl)thiazolidine-2-thiones (I), which dehydrate to the corresponding Δ4-thiazolines, isolated only as tetraacetates. A thiazolidine-2-thione forms also from the action of carbon disulphide on 1-N-methylamino-1-deoxy-D-fructose. l-Bromo-l-deoxy-2,3:4,5-di-O-isopropylidene-D-fructose is obtained by the action of dibromotriphenoxyphosphorane on 2,3:4,5-di-O-isopropylidene-D-fructose.Keywords
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