Obsevations on the cleavage of the bismuth–carbon bond in BiVcompounds: a new arylation reaction
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 246-247
- https://doi.org/10.1039/c39800000246
Abstract
Further examples of the selectivity of pentavalent trianyl-organobismuth oxidants are presented; deuterium labelling studies have established that the mechanism of oxidation of allylic alcohols by these reagents involves, to some extent, cleavage of the bismuth–aryl bond; several reactions involving the synthetically useful transfer of an aryl group from bismuth to nitrogen and to carbon are described.Keywords
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