Nuclear magnetic resonance. Slow rotation of a methyl group
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 830-831
- https://doi.org/10.1039/c39730000830
Abstract
The n.m.r. spectrum of the CH3 and CD2H groups in (3) and (4) respectively is temperature-dependent, indicating that the barrier to rotation of the methyl group is 7·2 kcal mol–1 at –131°.Keywords
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