Abstract
The reaction between (Z)‐1‐alkenyllithium and (E)‐β‐(N, N‐dialkylamino)‐α, β‐alkenals, (E)‐β‐(N, N‐dialkylamino)‐α, β‐alkenones or (E)‐β‐(N, N‐dialkylamino)‐α, β‐alkenoic esters yields mainly (E, Z)‐α, β‐γ, δ‐diunsaturated aldehydes, ketones, or esters and is therefore highly stereospecific.

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