Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters
- 29 May 2008
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 10 (13) , 2697-2700
- https://doi.org/10.1021/ol800829q
Abstract
The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO2 to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.Keywords
This publication has 46 references indexed in Scilit:
- Transformation of Carbon DioxideChemical Reviews, 2007
- Insertion of CO2into a palladiumallyl bond and a Pd(ii) catalysed carboxylation of allyl stannanesDalton Transactions, 2006
- Rhodium(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters with CO2Journal of the American Chemical Society, 2006
- Highly Enantioselective Catalytic Carbon Dioxide Incorporation Reaction: Nickel-Catalyzed Asymmetric Carboxylative Cyclization of Bis-1,3-dienesJournal of the American Chemical Society, 2004
- Novel Catalytic CO2 Incorporation Reaction: Nickel-Catalyzed Regio- and Stereoselective Ring-Closing Carboxylation of Bis-1,3-dienesJournal of the American Chemical Society, 2002
- Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and Allyl HalidesOrganometallics, 2000
- Recent developments in the activation of carbon dioxide by metal complexesCoordination Chemistry Reviews, 1999
- Palladium-Catalyzed Carboxylation of Allyl StannanesJournal of the American Chemical Society, 1997
- The Organometallic Chemistry of Carbon DioxideChemical Reviews, 1996
- Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexesChemical Reviews, 1988