Eine Neue Einfache Synthese von L-Vinelose
- 1 June 1985
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 4 (2) , 205-213
- https://doi.org/10.1080/07328308508058832
Abstract
Reduction of methyl 6-deoxy-2,3-0-isopropylidene-3-C-methyl-α-L-lyxo-hexopyranosid-4-ulose (2) with sodium tetrahydroborate or L-selectride produces exclusively the L-talo-configurated 4-hydroxy compound (3), which is transformed to methyl 6-deoxy-3,4-O-isopropylidene-3-C-methyl-α-L-talopyranoside (4). Methylation of the 2-hydroxy group and hydrolysis yields L-vinelose (6) .This publication has 8 references indexed in Scilit:
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