Cation-Electron Interaction in Metal-Ammonia Solutions
- 1 February 1961
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 34 (2) , 678-681
- https://doi.org/10.1063/1.1701009
Abstract
The problem of electron binding in the field of a cation in metal solutions is treated on the basis of an interstitial ion model. The energy levels and charge distribution of the unpaired electron are computed by a self-consistent field treatment for electron binding in a continuous dielectric medium employing one parameter wave function. Comparison with experimental results and with theoretical treatment based on a molecular model is presented. The adequacy of the continuous model is discussed.Keywords
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