Polycyclic fluoro-aromatic compounds. Part 10. Nucleophilic replacement of fluorine in heptafluoro-2-naphthyl-lithium
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2494-2496
- https://doi.org/10.1039/p19800002494
Abstract
Heptafluoro-2-naphthyl-lithium, prepared from 2H-heptafluoronaphthalene, reacts with an excess of butyl-lithium to give a 4 : 1 mixture of 6-butyl- and 7-butyl-hexafluoro-2-naphthyl-lithium. Carbonation, bromination, and hydrolysis of all the lithio-compounds gave the expected products.Keywords
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