Determination of the Self-diffusion Coefficient of Nickel Atoms in Nickel Sulfide

Abstract
The self-diffusion coefficient of ions or atoms in such crystals as halides, oxides and sulfides can be determined from the rate of the diffusion-controlled solid-state reaction as well as by the tracer method. In the present study, the self-diffusion coefficient of nickel atoms in nickel sulfide was determined from the rates of the sulfidation and desulfidation of nickel sulfide in H2S-H2gas mixtures. The results agreed well with the data obtained by the previous investigators employing the tracer technique.

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