Epimerization of α- to β-C-glucopyranosides under mild basic conditions
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 7,p. 1275-1280
- https://doi.org/10.1039/p19890001275
Abstract
A number of β-C-glucopyranosides having an activated methylene or methine group bonded to the anomeric carbon are obtainable in quantitative yield from the corresponding α-isomers by simple equilibration catalysed by various bases at room temperature.This publication has 2 references indexed in Scilit:
- New Methods for the Synthesis of Glycosides and Oligosaccharides—Are There Alternatives to the Koenigs‐Knorr Method? [New Synthetic Methods (56)]Angewandte Chemie International Edition in English, 1986
- C-Glycosidation of pyridyl thioglycosidesJournal of the American Chemical Society, 1985