The electronic configuration and oxygenation of NN′-ethylenebis(salicylaldehydeiminato)cobalt(II) studied by electron spin resonance spectroscopy
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 489-490
- https://doi.org/10.1039/c39720000489
Abstract
An e.s.r. study of [Co(salen)] in different solvents revealed that the electronic configuration (dyz)2(dzx)2(dxy)2(dz2)1(dx2–y2)0 is required for the compound to be able to oxygenate, while another configuration (dyz)2(dzx)2-(dz2)2(dx2–y2)0 which is realized in certain solvents does not permit oxygenation of the compound at room temperature.Keywords
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