Nature of the Unpaired Electron Orbital in Some Low Spin Oxygen-Co Complexes
- 1 January 1968
- journal article
- research article
- Published by Taylor & Francis in Spectroscopy Letters
- Vol. 1 (1) , 49-54
- https://doi.org/10.1080/00387016808049943
Abstract
The CoII complexes, Co(II)-bissalicylal-3,3′-diimino-di-n-propylamine peroxide I and decaammine-μ-peroxodicobalt cation II, were investigated by the electron spin resonance (esr). On the basis of the observed esr parameters, it was concluded that the unpaired electron is largely localized on the O2 group and, therefore, these complexes are better described as super-oxides. The equilibrium in solution of I between the paramagnetic and dia-magnetic forms implied by the previous studies was also demonstrated.Keywords
This publication has 7 references indexed in Scilit:
- The Molecular Structure of a Peroxo-Bridged Dicobalt CationJournal of the American Chemical Society, 1966
- Electron Spin Resonance of Tetraphenylporphine ChelatesThe Journal of Chemical Physics, 1965
- Paramagnetic Resonance Absorption in Peroxo-Dicobalt ComplexesThe Journal of Physical Chemistry, 1959
- Paramagnetic resonance in sodium and potassium superoxidesJournal of Computers in Education, 1955
- Chemistry of the Metal Chelate CompoundsSoil Science, 1952
- The Oxygen-Carrying Synthetic Chelate Compounds. VI. Equilibrium in SolutionJournal of the American Chemical Society, 1946
- The Oxygen-carrying Synthetic Chelate Compounds. IV. Magnetic Properties1Journal of the American Chemical Society, 1946