THE PAPILIONACEOUS ALKALOIDS: XIV. CONCERNING SPATHULATINE AND NONALUPINE
- 1 November 1951
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 29 (11) , 959-963
- https://doi.org/10.1139/v51-111
Abstract
The two alkaloids nonalupine and spathulatine reported in the literature have been found to be identical and to consist of the monohydrochloride of pusilline, C15H28N2. On heating invacuo the hydrochloride undergoes disproportionation, giving rise to the free base and the dihydrochloride. The peculiar reactions of spathulatine are explained by the fact that they simply liberated the base from its salt. Pusilline forms a dipicrate containing an additional mole of picric acid, which accounts for the necessity of using a solution of that acid for its recrystallization.This publication has 1 reference indexed in Scilit:
- Lupine Studies. XV.1 The Alkaloids of Lupinus sericeus PurshJournal of the American Chemical Society, 1940