Binary Supported Nickel Catalysts for the Deuterium Exchange Reaction between Hydrogen and Water Vapour
- 1 January 1982
- journal article
- research article
- Published by Taylor & Francis in Isotopenpraxis Isotopes in Environmental and Health Studies
- Vol. 18 (4) , 131-132
- https://doi.org/10.1080/10256018208544713
Abstract
Nickel catalysts supported by Fe2O3, CuO, MnO and CcO were prepared from the corresponding metal nitrates. Chemical treatment of the catalysis teas carried out at room temperature, while thermal treatment was made at 350 °C. The total surface area of the catalysts were measured by nitrogen adsorption at – 195 °C using the BET-equation. The specific metallic surface area was measured by hydrogen chemisorption at liquid temperature. The activity of the catalysis as tested for the isotopic exchange reaction of deuterium between hydrogen and water vapour. The results obtained showed that Ni – Fe2O3, Ni – CuO and Ni – MnO catalysts exhibit catalytic activity for the deuterium exchange between hydrogen and water vapour, while the catalyst supported with CeO has no activity for such an isolopic exchange reaction.Keywords
This publication has 10 references indexed in Scilit:
- Reactivation of Promoted Nickel Catalysts for Deuterium Exchange between Hydrogen and Water in the Vapour PhaseIsotopenpraxis Isotopes in Environmental and Health Studies, 1980
- Nickel/Chromium Oxide/Magnesium Oxide-Mixed Catalysts for Deuterium Exchange between Hydrogen and Water VapourIsotopenpraxis Isotopes in Environmental and Health Studies, 1977
- Separation of Deuterium Isotope by Chemical Exchange between Hydrogen and Water VapourIsotopenpraxis Isotopes in Environmental and Health Studies, 1974
- Catalytic studies of the gaseous exchange Reaction H2/HDO using Platinum on CharcoalZeitschrift für anorganische und allgemeine Chemie, 1972
- Hochwirksame ternäre Ni-Cr2O3-Al2O3-Mischkatalysatoren für den Deuteriumaustausch zwischen Wasserstoff und WasserdampfIsotopenpraxis Isotopes in Environmental and Health Studies, 1972
- The promoting action of chromia for nickel catalystsJournal of Catalysis, 1967
- CHEMISORPTION STUDIES ON SUPPORTED PLATINUMThe Journal of Physical Chemistry, 1962
- THE PHYSICAL NATURE OF SUPPORTED PLATINUMThe Journal of Physical Chemistry, 1960
- DISPERSION OF PLATINUM ON SUPPORTED CATALYSTSThe Journal of Physical Chemistry, 1960
- THE USE OF VAN DER WAALS ADSORPTION ISOTHERMS IN DETERMINING THE SURFACE AREA OF IRON SYNTHETIC AMMONIA CATALYSTSJournal of the American Chemical Society, 1935