Mechanism of the redox isomerisation of af-dichloro-bc-bis(pyridine)-de-trimethyleneplatinum(IV) to the platinum(II) complex of pyridinium propylide [PtCl2(C5H5NCHEt)(py)]
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 102-105
- https://doi.org/10.1039/dt9730000102
Abstract
Kinetic and other results on the reaction of af-dichloro-bc-bis(pyridine)-de-trimethyleneplatinum(IV) in benzene forming the platinum(II) ylide trans-[PtCl2(C5H5NCHEt)(py)] are presented; a dissociative mechanism is suggested.Keywords
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