Synthesis of the First Methylidyne‐Rhodium Cluster by Proton‐Induced H2/CH4‐Elimination from a μ‐Methylene Complex
- 1 August 1980
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 19 (8) , 651-653
- https://doi.org/10.1002/anie.198006511
Abstract
The transformation of a μ‐methylene‐dirhodium complex into a μ3‐methylidyne‐trirhodium complex (X‐ray structure analysis) has been accomplished in reaction (1) → (3). The first step is protonation of (1) to form the (isolable) μ‐hydrido complex (2). equation imageKeywords
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