Halides, Oxides, and Sulfides of the Transition Metals
- 1 October 1961
- journal article
- research article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 32 (10) , 2195-2197
- https://doi.org/10.1063/1.1777041
Abstract
The electrical conductivity and optical absorption data for many compounds of the transition metals suggest that there is a trend from ionic insulators, to metals, to covalent semiconductors as the overlap of atomic orbitals is increased. In this paper it is shown that a correlation exists between the electrical behavior of insulators and metals and the magnitude of the overlap integrals S(dεdε) and S(dεpπ).This publication has 6 references indexed in Scilit:
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- Oxides Which Show a Metal-to-Insulator Transition at the Neel TemperaturePhysical Review Letters, 1959
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- Electrical Properties of MolybdeniteProceedings of the Physical Society. Section B, 1953
- Some Overlap Integrals Involving d OrbitalsThe Journal of Chemical Physics, 1953