E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CHNH2
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1069-1071
- https://doi.org/10.1039/c39880001069
Abstract
The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.Keywords
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