An efficient synthesis of chiral quaternary carbon centres with high optical purity via 1,3-chirality transfer
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1596-1598
- https://doi.org/10.1039/c39870001596
Abstract
An efficient synthesis of chiral quaternary carbon centres via Me2Cu(CN)Li2·BF3 or RCu(CN)Li·BF3(R ≠ Me) mediated 1,3-chirality transfer of α-alkyl-γ-mesyloxy-α,β-enoates is reported.Keywords
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